Discussion and Reply Lithostratigraphic revision and correlation of the Oligo‐Miocene Murray Supergroup,western Murray Basin,South Australia     

P. A. Rogers  J. J. Lukasik  N. P. James 《Australian Journal of Earth Sciences》2013,60(3):485-486

Sequence‐stratigraphic interpretations of the 4200 m‐thick Palaeoproterozoic (1700–1650 Ma) Mt Isa Group and underlying Surprise Creek Formation identify three unconformity‐bounded packages termed the Prize, Gun and Loretta Supersequences. Siliciclastic rocks of the Surprise Creek Formation and Warrina Park Quartzite comprise the Prize Supersequence. Rapid facies changes from proximal, conglomeratic fluvial packages to distal, fine‐grained and deep‐water, rhythmites characterise this supersequence. Conglomeratic intervals in the Mt Isa area reflect syndepositional movement along basin‐margin faults during the period of supersequence initiation. A major unconformity, which extends over a period of about 25 million years, separates the Gun and Prize Supersequences. In the Leichhardt River Fault Trough uplift and incision of Prize sedimentary rocks coincided with emplacement of the Sybella Granite (1671±8 Ma) and Carters Bore Rhyolite (1678±2 Ma) and the removal of an unknown thickness of Prize Supersequence section. Deep‐water, turbiditic rhythmites of the Mt Isa Group dominated the Gun and Loretta Supersequences. Tempestites are present over discrete intervals and represent times of relative shallowing. High accommodation and sedimentation rates at the base of the Gun Supersequence resulted in the deposition of transgressive nearshore facies (uppermost Warrina Park Quartzite) overlain by a thick interval of deep‐water, siltstone‐mudstone rhythmites of the Moondarra Siltstone and Breakaway Shale. With declining rates of siliciclastic sedimentation and shallowing of the succession, calcareous sediments of the Native Bee Siltstone prograded over the deeper water deposits. Two third‐order sequences, Gun 1 and 2, characterise these lower parts of the Gun Supersequence. An increase in accommodation rates near the top of the Native Bee Siltstone in Gun 3 time, resulted in a return to deep‐water sedimentation with deposition of dolomitic rhythmites of the Urquhart Shale and Spear Siltstone. The Pb–Zn–Ag ore‐hosting interval of the Urquhart Shale is interpreted to occur in progradational highstand deposits of the Gun 3 Sequence. In the Leichhardt River Fault Trough the Loretta Supersequence boundary forms a correlative conformity. Coarser grained and thicker bedded sediments of the Kennedy Siltstone comprise lowstand deposits at the base of this cycle. These sediments fine up into the transgressive, deep‐water, siliciclastic facies of the Magazine Shale, which in turn are truncated against the Mt Isa Fault.  相似文献   

Heavy-metal loadings related to urban contamination in the Kooloonbung Creek catchment,Port Macquarie,New South Wales     

P. M. Ashley  M. E. Napier 《Australian Journal of Earth Sciences》2013,60(6):843-862

Urbanisation and industrial development lead to contamination of estuaries and streams with dispersed loadings of heavy metals and metalloids. Contributions of these elements also occur from natural sources. This study provides baseline geochemical data on the respective natural and anthropogenic inputs of Cu, Pb, Zn, Cd, As, Sb, Cr, Ni, Mn and S to estuarine, fluvial and wetland sediments, and adjacent soils, in the Kooloonbung Creek catchment that drains the Port Macquarie urban area in north coastal New South Wales. There have been anthropogenic additions of Cu, Pb, Zn and As from dispersed urban sources at Port Macquarie, but they are restricted to the local catchment and do not impact on the adjacent Hastings River estuary. The most contaminated sediments display enrichment factors up to 20 × for Cu and Pb, 9 × for Zn and 5 × for As relative to local background values. However, only one value (for Pb) exceeds National Water Quality Management Strategy interim sediment quality guideline (high) values. On the other hand, sediments and local soils are commonly strongly enriched in Cr, Ni and Mn, reflecting adjacent ultramafic and mafic rock substrate and lateritic regolith. Concentrations of Cr and Ni are commonly well above interim sediment quality guideline (high) values for sediments, but are in mineralogical forms that are not readily bioavailable. Sediment and soil quality guideline values consequently need to recognise natural enrichments and the mineralogical siting of heavy metals. Although dissolved concentrations of heavy metals in stream waters are commonly low, there is evidence for mobility of Cu, Zn, Fe and Al. Parts of the Kooloonbung Creek wetland area lie on sulfidic estuarine sediments (potential acid sulfate soils). Experimental oxidation of uncontaminated and contaminated sulfidic sediments leads to substantial dissolution of heavy metals under acid conditions, with subsequent aquatic mobility. The results warn about disturbance and oxidation of potential acid sulfate soils that have been contaminated by urban and natural heavy-metal sources.  相似文献   

德兴铜矿地区土壤的基本特征及其对重金属元素的吸附研究     

李子悦  吴沣  郝瑞霞 《岩石矿物学杂志》2013,32(6):1013-1021

本文首先分析了江西德兴铜矿区周围土壤的微量元素和矿物组成特征,结果显示该地区重金属元素富集,且表层土中重金属元素含量与粘土矿物相对含量变化具有较好的一致性。室内土柱淋滤实验结果表明,当总淋滤时间为451 h时,土壤对Pb²⁺的总吸附量为2 584.75 mg/kg,淋滤实验的前半期存在多种竞争吸附机制,后半期土壤对Pb²⁺的吸附基本达到动态平衡。淋滤后土壤矿物的相对质量分数发生了改变,粘土矿物有所减少。粘土矿物在不同土壤层对Pb²⁺的吸附能力也各异。  相似文献   

岩溶型尾矿库渗滤液重金属污染防治技术研究进展     

肖筱瑜  李蘅  张静  徐文炘 《矿产与地质》2013,(2):173-176

文章通过对岩溶型尾矿库渗滤液重金属污染防治技术相关方法进行研究,结果表明可渗透反应墙(PRB)处理污染地下水具有初期建设投资低、可以根据所要处理的污染物质灵活选择、运行期不需要能量供给而且处理设施不会占用宝贵的土地资源等显著优点,是岩溶型尾矿渗滤液治理方面最具发展前景的方法之一。  相似文献   

Ultrasound‐Assisted Emulsification–Microextraction Combined with Graphite Furnace Atomic Absorption Spectrometry for the Determination of Trace Lead in Water     

Hongmei Jiang  Yu Zhang  Bocheng Qiu  Wenhua Li 《洁净——土壤、空气、水》2012,40(4):438-443

The ultrasound‐assisted emulsification–microextraction (USAEME) method was combined with graphite furnace atomic absorption spectrometry (GFAAS) for the determination of trace Pb using dithizone (H²DZ) as chelating reagent. Some effective parameters influenced the detection and microextraction, such as ashing temperature and atomization temperature, pH, extraction solvent, sample volume, extraction time, and extraction temperature were selected and optimized. After extraction, the calibration curves for Pb was in the concentration range of 0.1–10 ng mL^?1, and the linear equation was y = 0.097 x + 0.023 (R = 0.99). Under the optimized conditions, the detection limit of the method was 20 pg mL^?1 with an enrichment factor of 70 and the relative standards deviation (RSD) for seven determinations of 1 ng mL^?1 Pb was 11%. The proposed method was successfully applied to determine trace Pb in Yueya Lake water, pond water, and spiked samples. Furthermore, a certified reference material of Environment Water (GBW08607) was analyzed and the determined value was in good agreement with the certified value, which showed the accuracy, recovery, and applicability of the reported method.  相似文献   

基于精密探测的金属矿山采空区群稳定性分析     

宋卫东  付建新  杜建华  张朝雷 《岩土力学》2012,33(12):3781-3787

采空区群的稳定性分析是一个复杂的地质问题,而在区域内存在一种群效应。准确地掌握采空区群的三维形态和空间的相对位置是进行稳定性分析的前提。以石人沟铁矿为背景,利用空区探测系统（CMS）对采空区进行了精密探测,并对探测数据进行处理和转换,在此基础上,应用3Dmine建立了采空区群的三维空间模型,经过进一步处理实现了与FLAC3D的耦合,建立了三维数值计算模型。根据计算结果对采空区群区域的应力场、位移场进行了分析,对群区域内的群效应进行了阐述。在此基础上对群区域地表位移进行了分析,确定了地表最大位移面积和采空区水平面积的比值。研究结果表明,区域内的群效应使应力和位移较单个采空区时都有了较大增加,且增加幅度并不是单纯的叠加,这种效应加剧了采空区的危险等级,将CMS、3Dmine和FLAC3D三者的优势结合起来,为采空区群得稳定性分析提供了一个准确而有效的途径。  相似文献   

施用不同畜禽粪便土壤剖面中重金属分布特征   总被引：8，自引：0，他引：8  

叶必雄  刘圆  虞江萍  杨林生  李永华  王五一  欧阳竹 《地理科学进展》2012,31(12):1708-1714

针对不同粪便集中施用情况, 选取禹城市3 个畜禽养殖区, 通过采集不同旱地农田土壤剖面样品, 研究典型重金属元素随粪便施用程度的变化、土壤剖面中重金属垂直分布特征以及施用不同畜禽粪便土壤剖面中重金属分布的差异。结果发现,长期施用畜禽粪便土壤剖面中重金属Cu、Zn、Pb、Cr、As的含量要高于未施用畜禽粪便的对照土壤剖面, 其中Cu、Zn 超过对照组较大;偶尔施用畜禽粪便土壤剖面Cu、Zn、Pb、Cr、As 的含量低于长期施用畜禽粪便土壤剖面, 且与未施用畜禽粪便的对照土壤剖面相差不大。牛粪集中施用区土壤剖面中Cu、Pb、Cr、Cd、Ni 等重金属存在较为明显的淋溶下移性, Hg、As两元素存在较为明显的表层或亚表层聚集现象;猪粪集中施用区土壤剖面各重金属除Cr、Ni 外, 都显示出较为明显的表层或亚表层聚集现象;鸡粪集中施用区的土壤剖面Cu、Pb、Cd、Cr、Ni 存在一定的淋溶下移性, 而Zn、Hg、As等3 种元素存在显著表层亚表层聚集现象。长期施用不同畜禽粪便的不同土壤剖面Cr、Ni、Cd、Pb 等含量变化差异明显, 而As、Hg差异性不显著;施牛粪与施鸡粪剖面中的Zn, 施猪粪与施鸡粪剖面中的Cu差异也不显著。  相似文献   

基于高分卫星遥感数据的金属矿开发现状及环境问题研究——以江西省德兴多金属矿集区为例   总被引：4，自引：3，他引：1       下载免费PDF全文

李丽  汪洁  汪劲  王昊  荆青青 《中国地质调查》2016,3(5):60-66

为及时、准确地掌握金属矿山的开发状况,有针对性地对金属矿山开发引起的环境问题进行恢复治理,以ZY-3等高分辨率卫星遥感数据为信息源,对江西省上饶市德兴多金属矿集区金属矿的开采状况及引发的环境问题进行了研究。在广泛收集矿区地质矿产资料、地形资料和遥感资料的基础上,结合露天开采、地下开采、联合开采等不同开采方式的金属矿的影像特征和实地调查验证,建立了金属矿开发占地的直接和间接解译标志; 根据各类矿山地物的影像特征和解译标志,对研究区金属矿山开采情况和环境状况进行目视解译和人机交互解译,获取了研究区内各时相的矿山开发状况和环境状况信息; 利用ArcGIS平台中空间分析模块功能对各类开发占地的面积进行了统计分析; 根据统计数据对研究区的金属矿开采状况及其诱发的地质灾害、植被破坏、污染水体和固体废弃物等矿山环境问题进行分析,指明研究区矿山环境问题的研究现状及发展趋势,有针对性地提出建议,为矿山环境监测和矿山环境恢复治理工程提供参考依据。  相似文献   

渭北煤田下峪口矿二叠纪煤中稀土元素地球化学研究     

崔晓南  黄文辉  敖卫华  周鸿璞  梁飞 《地学前缘》2016,23(3):90-96

运用电感耦合等离子体质谱（ICP MS）对渭北煤田韩城下峪口矿二叠纪主采煤层及其顶底板中的稀土元素进行了测定。在此基础上,全面分析了稀土元素的含量特征和分布模式,探讨渭北煤田二叠纪煤中稀土元素的主要来源及赋存状态。结果表明：与华北和中国煤均值相比,本区煤层中稀土元素相对不富集,∑REY平均含量为87.70 μg/g;剖面上,2号煤中稀土含量稍高于3号煤,3号煤层中自上而下,稀土元素含量呈降低的趋势,在顶底板中出现富集。研究区煤层中轻稀土元素相对于重稀土元素明显富集,Ce呈微弱正异常,成煤沼泽受海水的影响程度较小。Eu明显负异常,且∑REY含量与CaO含量呈负相关关系,说明当时的成煤环境为酸性还原环境。煤层与其顶底板样品中稀土元素分布模式相似,成煤期间物质来源基本一致,陆源物质供应相对稳定。煤中稀土元素含量与灰分呈不太显著的正相关关系（R=0.216）,表明煤中稀土元素可能以无机态和有机吸附态共存。  相似文献   

重庆龙潭组煤中稀土元素地球化学及地质成因分析     

郭江峰  姚多喜  陈健  陈萍 《地学前缘》2016,23(3):51-58

运用电感耦合等离子体质谱(ICP MS)、X射线荧光光谱(XRF)、X射线衍射(XRD)等方法对重庆龙潭组煤中稀土元素的地球化学特征进行研究。结果表明,各煤样稀土元素分布模式相似,总体呈左高右低的宽缓的“V”型曲线,轻稀土曲线段“右倾”,重稀土曲线段较为“平坦”,成煤沼泽受陆源碎屑影响较大。南桐5#煤稀土元素含量高,接近全国平均值的2倍,受汉南古陆、大巴山古陆和龙门山岛屿控制,少量陆源碎屑物来自康滇古陆。东林6#煤中的稀土元素含量低于全国平均值水平,海水作用明显,煤样中稀土元素含量未受碱性火山灰的影响,但其底板受碱性火山灰影响强烈。根据煤层稀土元素含量及其比值分析,研究区龙潭组为海湾/潟湖潮坪及浅海碳酸盐沉积的沉积环境。  相似文献